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Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/148262
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dc.contributor.authorLorusso, Giulia-
dc.contributor.authorEvangelisti, Marco-
dc.contributor.authorTasiopoulos, Anastasios J.-
dc.date.accessioned2017-04-11T10:11:40Z-
dc.date.available2017-04-11T10:11:40Z-
dc.date.issued2016-
dc.identifierdoi: 10.1002/anie.201509461-
dc.identifiere-issn: 1521-3773-
dc.identifierissn: 1433-7851-
dc.identifier.citationAngewandte Chemie International Edition 55(2): 679-684 (2016)-
dc.identifier.urihttp://hdl.handle.net/10261/148262-
dc.descriptionet al.-
dc.description.abstractTwo nanosized Mn and MnNa clusters based on analogues of the high-spin (S=22) [Mn Mn (μ-O)] supertetrahedral core are reported. Mn and MnNa complexes consist of eight and four decametallic supertetrahedral subunits, respectively, display high virtual symmetry (O), and are unique examples of clusters based on a large number of tightly linked high nuclearity magnetic units. The complexes also have large spin ground-state values (Mn: S=61/2; MnNa: S=51/2) with the Mn cluster displaying single-molecule magnet (SMM) behavior and being the second largest reported homometallic SMM.-
dc.description.sponsorshipThis work was supported by the Cyprus Research Promotion Foundation grant ANABAVMISH/PAGIO/0308/12 which is co-funded by the Republic of Cyprus and the European Regional Development Fund, the US National Science Foundation (Grant DMR-1213030 to G.C.), and the Spanish MINECO (Project FEDER-MAT2012-38318-C03-01).-
dc.publisherWiley-VCH-
dc.relation.isversionofPostprint-
dc.rightsopenAccess-
dc.subjectO ligands-
dc.subjectSingle-molecule magnets-
dc.subjectManganese-
dc.subjectCluster compounds-
dc.subjectMagnetic properties-
dc.titleMagnetic "Molecular Oligomers" based on decametallic supertetrahedra: A giant Mn49 cuboctahedron and its Mn25Na4 fragment-
dc.typeartículo-
dc.identifier.doi10.1002/anie.201509461-
dc.relation.publisherversionhttps://doi.org/10.1002/anie.201509461-
dc.date.updated2017-04-11T10:11:40Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderNational Science Foundation (US)-
dc.contributor.funderEuropean Commission-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderResearch Promotion Foundation-
dc.relation.csicSí-
dc.identifier.funderhttp://dx.doi.org/10.13039/100000001es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100001810es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.grantfulltextopen-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
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