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Título:	Magnetic "Molecular Oligomers" based on decametallic supertetrahedra: A giant Mn49 cuboctahedron and its Mn25Na4 fragment
Autor:	Lorusso, Giulia CSIC ORCID; Evangelisti, Marco CSIC ORCID ; Tasiopoulos, Anastasios J.
Palabras clave:	O ligands Single-molecule magnets Manganese Cluster compounds Magnetic properties
Fecha de publicación:	2016
Editor:	Wiley-VCH
Citación:	Angewandte Chemie International Edition 55(2): 679-684 (2016)
Resumen:	Two nanosized Mn and MnNa clusters based on analogues of the high-spin (S=22) [Mn Mn (μ-O)] supertetrahedral core are reported. Mn and MnNa complexes consist of eight and four decametallic supertetrahedral subunits, respectively, display high virtual symmetry (O), and are unique examples of clusters based on a large number of tightly linked high nuclearity magnetic units. The complexes also have large spin ground-state values (Mn: S=61/2; MnNa: S=51/2) with the Mn cluster displaying single-molecule magnet (SMM) behavior and being the second largest reported homometallic SMM.
Descripción:	et al.
Versión del editor:	https://doi.org/10.1002/anie.201509461
URI:	http://hdl.handle.net/10261/148262
DOI:	10.1002/anie.201509461
Identificadores:	doi: 10.1002/anie.201509461 e-issn: 1521-3773 issn: 1433-7851
Aparece en las colecciones:	(ICMA) Artículos

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Magnetic "Molecular Oligomers" based on decametallic supertetrahedra: A giant Mn49 cuboctahedron and its Mn25Na4 fragment