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Title

The microbiological transformation of some ent-beyerene diterpenoids by Gibberella fujikuroi to beyergibberellins and beyerenolides

AuthorsDíaz, Carmen E. ; Fraga, Braulio M. ; González, Antonio G.; Hanson, James R.; Hernández, Melchor G.; San Martín, Aurelio
KeywordsGibberella fujikuroi
Gibberellins
ent-beyer-15-ene
Beyergibberellins
Beyerenolides
Issue Date1985
PublisherElsevier
CitationPhytochemistry 24(7): 1489-1491 (1985)
AbstractThe microbiological transformation by Gibberelia fujikuroi of ent-beyer-15-ene into the beyergibberellins A9 and A13, 7β-hydroxy- and 7β,18-dihydroxybeyerenolides, and of ent-beyer-15-en-19-ol into beyergibberellins A4, A7, A9, A13 and A25,and 7β-hydroxy-and 7β,18-dihydroxybeyerenolides is described. In contrast, ent-beyer-15-en-18-ol gave ent-7α, 18,19-trihydroxybeyer-15-ene, 7β,18-dihydroxybeyerenolide and ent-7α,18-dihydroxybeyer-15-en-19-oic acid again revealing the inhibitory effect of an 18-hydroxyl group on oxidative transformations at C-6β by Gibberella fujikuroi.
Description3 pages, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1016/S0031-9422(00)81050-X
URIhttp://hdl.handle.net/10261/14794
DOI10.1016/S0031-9422(00)81050-X
ISSN0031-9422
Appears in Collections:(IPNA) Artículos
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