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dc.contributor.author | Martínez-Salvador, Sonia | - |
dc.contributor.author | Falvello, Larry R. | - |
dc.contributor.author | Martín, Antonio | - |
dc.contributor.author | Menjón, Babil | - |
dc.date.accessioned | 2017-03-30T06:57:01Z | - |
dc.date.available | 2017-03-30T06:57:01Z | - |
dc.date.issued | 2015 | - |
dc.identifier | doi: 10.1039/c5sc01578b | - |
dc.identifier | e-issn: 2041-6539 | - |
dc.identifier | issn: 2041-6520 | - |
dc.identifier.citation | Chemical Science 6(10): 5506-5510 (2015) | - |
dc.identifier.uri | http://hdl.handle.net/10261/147566 | - |
dc.description | Open Access Article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | - |
dc.description.abstract | The hexanuclear gold carbonyl cluster [PPh4]2[Au6(CF3)6Br2(CO)2] (4) has been obtained by spontaneous self-assembly of the following independent units: CF3AuCO (1) and [PPh4][Br(AuCF3)2] (3). The cyclo-Au6 aggregate 4, in which the components are held together by unassisted, fairly strong aurophilic interactions (Au⋯Au ∼310 pm), exhibits a cyclohexane-like arrangement with chair conformation. These aurophilic interactions also result in significant ν(CO) lowering: from 2194 cm−1 in the separate component 1 to 2171 cm−1 in the mixed aggregate 4. Procedures to prepare the single-bridged dinuclear component 3 as well as the mononuclear derivative [PPh4][CF3AuBr] (2) are also reported. | - |
dc.description.sponsorship | This work was supported by the Spanish MINECO/FEDER (Project CTQ2012-35251), and the Gobierno de Aragón (Grupo Consolidado E21: Química Inorganica y de los Compuestos Organometalicos). | - |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.relation.isversionof | Publisher's version | - |
dc.rights | openAccess | - |
dc.title | A hexanuclear gold carbonyl cluster | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1039/c5sc01578b | - |
dc.relation.publisherversion | https://doi.org/10.1039/c5sc01578b | - |
dc.date.updated | 2017-03-30T06:57:01Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.rights.license | http://creativecommons.org/licenses/by-nc/3.0/ | - |
dc.contributor.funder | Gobierno de Aragón | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100010067 | es_ES |
dc.identifier.pmid | 28717445 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
Aparece en las colecciones: | (ISQCH) Artículos (ICMA) Artículos |
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goldcarbonclus.pdf | 227,64 kB | Adobe PDF | Visualizar/Abrir |
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