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Título

TTF-PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

AutorSouto Salom, Manuel ; Rovira, Concepció ; Ratera, Immaculada ; Veciana, Jaume
Fecha de publicación14-ene-2017
EditorRoyal Society of Chemistry (Great Britain)
CitaciónCrystEngComm 19(2): 197- 206 (2017)
ResumenOrganic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF-π-PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.
URIhttp://hdl.handle.net/10261/144046
DOI10.1039/C6CE01660J
Identificadoresdoi: http://dx.doi.org/10.1039/C6CE01660J
issn: 1466-8033
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