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Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/144046
Título : TTF-PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state
Autor : Souto Salom, Manuel; Rovira Angulo, Concepció; Ratera Bastardas, Immaculada; Veciana Miró, Jaume
Fecha de publicación : 14-ene-2017
Editor: Royal Society of Chemistry (Great Britain)
Citación : CrystEngComm 19(2): 197- 206 (2017)
Resumen: Organic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF-π-PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.
URI : http://hdl.handle.net/10261/144046
Identificadores: doi: http://dx.doi.org/10.1039/C6CE01660J
issn: 1466-8033
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