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Título: | Synthesis, x-ray structure and reactivity of a sterically protected azobisphenol ligand: on the quest for new multifunctional active ligands |
Autor: | Evangelio, Emi CSIC; Saiz-Poseu, Javier CSIC ORCID; Maspoch, Daniel CSIC ORCID ; Wurst, Klaus; Busqué, Félix; Ruiz Molina, Daniel CSIC ORCID | Palabras clave: | Acid–base behaviour Multifunctional ligands Valence tautomerism Chromophores Azobisphenol ligand |
Fecha de publicación: | 2008 | Editor: | John Wiley & Sons | Citación: | European Journal of Inorganic Chemistry (14): 2278-2285 (2008) | Resumen: | Different synthetic routes have been explored for the synthesis of the sterically protected 2,2'-dihydroxy-4,3,4,3'-tetratert-butylazobenzene ligand (2), which is an excellent candidate for the development of valence tautomeric complexes. As expected, such a ligand exhibits good reactivity with transition-metal ions, as shown by the synthesis and characterization of the new cobalt complex [Co(22–)(H2O)3]Cl·2.5EtOH·H2O (8). This fact together with the reversible deprotonation/protonation of the phenol groups has been used to create a chromophoric array of three states with significantly different colours, which can interconvert reversibly between them. | URI: | http://hdl.handle.net/10261/143092 | DOI: | 10.1002/ejic.200701339 | Identificadores: | doi: 10.1002/ejic.200701339 issn: 1434-1948 e-issn: 1099-0682 |
Aparece en las colecciones: | (ICMAB) Artículos (CIN2) Artículos |
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