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Título: | Intramolecular electron transfer in the mixed-valence [Co(3,5-DTBCat)(3,5-DTBSQ)(bpy)] complex: Beyond valence tautomerism |
Autor: | Evangelio, Emi CSIC; Hendrickson, David N.; Ruiz Molina, Daniel CSIC ORCID | Palabras clave: | Redox active ligand Radicals Electron transfer Mixed-valence |
Fecha de publicación: | 2008 | Editor: | Elsevier | Citación: | Inorganica Chimica Acta 361(12-13): 3403-3409 (2008) | Resumen: | The series of complexes [Co(Q)2(bpy)]n (n = -1, 0, +1) that can be derived by partial reduction or oxidation of complex 1, ls-Co(III) has been synthesized and studied. The results support the theoretical calculations which pointed to an intervalence transfer (IT) from the Cat2- to the SQ- ligand rather than a LMCT transition as the origin for the low-energy band transition centered at 2500 nm observed for 1, ls-Co(III). | URI: | http://hdl.handle.net/10261/143078 | DOI: | 10.1016/j.ica.2008.02.069 | Identificadores: | doi: 10.1016/j.ica.2008.02.069 issn: 0020-1693 |
Aparece en las colecciones: | (ICMAB) Artículos (CIN2) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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