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Title

Intramolecular electron transfer in the mixed-valence [Co(3,5-DTBCat)(3,5-DTBSQ)(bpy)] complex: Beyond valence tautomerism

AuthorsEvangelio, Emi ; Hendrickson, David N.; Ruiz Molina, Daniel
KeywordsRedox active ligand
Radicals
Electron transfer
Mixed-valence
Issue Date2008
PublisherElsevier
CitationInorganica Chimica Acta 361(12-13): 3403-3409 (2008)
AbstractThe series of complexes [Co(Q)2(bpy)]n (n = -1, 0, +1) that can be derived by partial reduction or oxidation of complex 1, ls-Co(III) has been synthesized and studied. The results support the theoretical calculations which pointed to an intervalence transfer (IT) from the Cat2- to the SQ- ligand rather than a LMCT transition as the origin for the low-energy band transition centered at 2500 nm observed for 1, ls-Co(III).
URIhttp://hdl.handle.net/10261/143078
DOI10.1016/j.ica.2008.02.069
Identifiersdoi: 10.1016/j.ica.2008.02.069
issn: 0020-1693
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(CIN2) Artículos
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