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Title

Synthesis of functionalized nitrogen heterocycles by radical decarboxylation of β- and γ-amino acids

AuthorsBoto, Alicia CSIC ORCID ; Hernández, Rosendo CSIC; León, Yolanda de; Murguía, José Ramón CSIC ORCID; Rodríguez-Afonso, Abigail
KeywordsAmino acids
Cleavage reactions
Halogenation
Nitrogen heterocycles
Radical reactions
Issue DateFeb-2005
PublisherJohn Wiley & Sons
CitationEuropean Journal of Organic Chemistry 2005(4): 673-682 (2005)
AbstractIodinated or oxygenated nitrogen heterocycles are obtained by radical decarboxylation of β- and γ-amino acids. This mild, versatile reaction is applied to the synthesis of bioactive products, such as 4-arylpiperidines, hydroxylated piperidines, and new antifungal agents.
Description10 pages, 1 figure, 2 tables, 9 schemes.-- Supporting information available: Synthesis and spectroscopic data of compounds 18–22 and 25 and the synthetic intermediates 44 and 45.
Publisher version (URL)http://dx.doi.org/10.1002/ejoc.200400698
URIhttp://hdl.handle.net/10261/13666
DOI10.1002/ejoc.200400698
ISSN1434-193X
E-ISSN1099-0690
Appears in Collections:(IPNA) Artículos

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