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dc.contributor.authorFrancisco, Cosme G.en_US
dc.contributor.authorGonzález Martín, Concepción C.en_US
dc.contributor.authorHerrera, Antonio J.en_US
dc.contributor.authorRodríguez Paz, Nievesen_US
dc.contributor.authorSuárez, Ernesto-
dc.date.accessioned2009-06-15T07:52:01Z-
dc.date.available2009-06-15T07:52:01Z-
dc.date.issued2006-11-07en_US
dc.identifier.citationTetrahedron Letters 47(51): 9057-9060 (2006)en_US
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10261/13657-
dc.description4 pages, 2 tables, 1 scheme.-- Printed version published Dec 18, 2006.-- Supporting information (33 pages Word file) available at: http://dx.doi.org/10.1016/j.tetlet.2006.10.086-
dc.description.abstractThe chemoselective radical reduction of the iodine atom in a series of 1-deoxy-1-halo-1-iodo-alditols with the 1-ethylpiperidine hypophosphite (EPHP)/AIBN system is described. EPHP is also a good chain carrier for the radical addition of gem-dihalocompounds to electron-deficient olefins. Thus, the synthesis of 4-halo-glycooctononitriles and 4-halo-glycoheptononitriles can be achieved by an intermolecular addition of the 1-deoxy-1-halo-alditol-1-yl radical intermediate to acrylonitrile.-
dc.description.sponsorshipThis work was supported by the Investigation programs No. CTQ2004-06381/BQU and CTQ2004-02367/BQU of the Ministerio de Educación y Ciencia, Spain, cofinanced with the Fondo Europeo de Desarrollo Regional (FEDER). N.R.P. and A.J.H. thank the Program I3P-CSIC for fellowships.-
dc.format.extent2373 bytes-
dc.format.extent122153 bytes-
dc.format.mimetypetext/plain-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherElsevier-
dc.rightsclosedAccessen_US
dc.titleChemoselective 1-ethylpiperidine hypophosphite (EPHP)-mediated intermolecular radical additions of 1-deoxy-1-halo-1-iodo-alditols to electron-deficient olefinsen_US
dc.typeartículoen_US
dc.identifier.doi10.1016/j.tetlet.2006.10.086-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.tetlet.2006.10.086-
dc.contributor.funderMinisterio de Educación y Ciencia (España)-
dc.contributor.funderEuropean Commission-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
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