Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/13657
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Chemoselective 1-ethylpiperidine hypophosphite (EPHP)-mediated intermolecular radical additions of 1-deoxy-1-halo-1-iodo-alditols to electron-deficient olefins |
Autor: | Francisco, Cosme G. CSIC; González Martín, Concepción C. CSIC ORCID ; Herrera, Antonio J. CSIC ; Rodríguez Paz, Nieves CSIC ; Suárez, Ernesto CSIC ORCID | Fecha de publicación: | 7-nov-2006 | Editor: | Elsevier | Citación: | Tetrahedron Letters 47(51): 9057-9060 (2006) | Resumen: | The chemoselective radical reduction of the iodine atom in a series of 1-deoxy-1-halo-1-iodo-alditols with the 1-ethylpiperidine hypophosphite (EPHP)/AIBN system is described. EPHP is also a good chain carrier for the radical addition of gem-dihalocompounds to electron-deficient olefins. Thus, the synthesis of 4-halo-glycooctononitriles and 4-halo-glycoheptononitriles can be achieved by an intermolecular addition of the 1-deoxy-1-halo-alditol-1-yl radical intermediate to acrylonitrile. | Descripción: | 4 pages, 2 tables, 1 scheme.-- Printed version published Dec 18, 2006.-- Supporting information (33 pages Word file) available at: http://dx.doi.org/10.1016/j.tetlet.2006.10.086 | Versión del editor: | http://dx.doi.org/10.1016/j.tetlet.2006.10.086 | URI: | http://hdl.handle.net/10261/13657 | DOI: | 10.1016/j.tetlet.2006.10.086 | ISSN: | 0040-4039 |
Aparece en las colecciones: | (IPNA) Artículos |
Mostrar el registro completo
CORE Recommender
SCOPUSTM
Citations
3
checked on 21-abr-2024
WEB OF SCIENCETM
Citations
3
checked on 27-feb-2024
Page view(s)
393
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.