English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/13461
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Efficient and selective removal of methoxy protecting groups in carbohydrates

AuthorsBoto, Alicia ; Hernández, Dácil ; Hernández, Rosendo ; Suárez, Ernesto
Issue Date21-Sep-2004
PublisherAmerican Chemical Society
CitationOrganic Letters 6(21): 3785-3788 (2004)
Abstract[Reaction: see text] The selective removal from carbohydrate substrates of methoxy protecting groups next to hydroxy groups is reported. On treatment with PhI(OAc)(2)-I(2), the methoxy group is transformed into an easily removable acetal. The mild conditions of this methodology are compatible with many functional groups, and good to excellent yields are usually achieved.
Description4 pages, 1 table, 4 schemes.-- PMID: 15469349 [PubMed].-- Printed version published Oct 14, 2004.
Supporting information available: Synthesis of substrate 12 and General Procedure for the one-pot protecting group transformation-hydrolysis. 1H and 13C NMR spectra and spectroscopic data for several compounds.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/ol048439%2B
Publisher version (URL)http://dx.doi.org/10.1021/ol048439+
URIhttp://hdl.handle.net/10261/13461
DOI10.1021/ol048439+
ISSN1523-7060
Appears in Collections:(IPNA) Artículos
Files in This Item:
There are no files associated with this item.
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.