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Diverted domino reactivity in tertiary skipped diynes: A convenient access to polyfunctionalized cyclohexadienones and multivalent aromatic scaffolds

AuthorsTejedor, David ; López-Tosco, Sara ; González-Platas, Javier; García-Tellado, Fernando
Issue Date26-Jul-2011
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 17: 9571-9575 (2011)
AbstractDiverting is the game! A new domino manifold has been implemented for the synthesis of cyclohexadienone-based scaffolds from tertiary skipped diynes and secondary amines. The manifold takes advantage of a new O-enolate-driven reactivity pattern discovered for these diynes. The scaffolds are conveniently transformed into the corresponding multivalent salicylate derivatives (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publisher version (URL)http://dx.doi.org/10.1002/chem.201101676
Identifiersissn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(IPNA) Artículos
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