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A microwave-assisted domino rearrangement of propargyl vinyl ethers to multifunctionalized aromatic platforms

AuthorsTejedor, David ; Méndez-Abt, Gabriela ; Cotos, Leandro ; Ramírez, Miguel A.; García-Tellado, Fernando
Issue Date15-Feb-2011
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 17: 3318-3321 (2011)
AbstractH makes a difference! A novel reactivity profile of propargyl vinyl ethers has been developed, which is controlled by the presence of a hydrogen atom at the homopropargylic position (see scheme; EWG=electron-withdrawing group). This strategy was conveniently used to construct multifunctionalized phenolic platforms, including salicylaldehydes and the corresponding ketone derivatives. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publisher version (URL)http://dx.doi.org/10.1002/chem.201003532
Identifiersissn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(IPNA) Artículos
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