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Title

Merging domino and redox chemistry: Stereoselective access to di- and trisubstituted β,γ-unsaturated acids and esters

AuthorsTejedor, David ; Méndez-Abt, Gabriela ; Cotos, Leandro ; García-Tellado, Fernando
Issue Date22-Feb-2012
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 18: 3468-3472 (2012)
AbstractMerging is the game! The coupling of a domino reaction and an internal neutral redox reaction constitutes an excellent manifold for the stereoselective synthesis of di- and trisubstituted olefins featuring a malonate unit, an ester, or a free carboxylic acid as substituents at the allylic position (see scheme; MW=microwave). The reaction utilizes simple starting materials (propargyl vinyl ethers), methanol or water as solvents, and a very simple and bench-friendly protocol. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publisher version (URL)http://dx.doi.org/10.1002/chem.201103763
URIhttp://hdl.handle.net/10261/132549
DOI10.1002/chem.201103763
Identifiersissn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(IPNA) Artículos
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