Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/13223
Share/Export:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

Geometry and halogen regiochemistry determination of vicinal vinyl dihalides by 1H and 13C NMR. Application to the structure elucidation of prefuroplocamioid, an unusual marine monoterpene

AuthorsDíaz-Marrero, Ana R. CSIC ORCID; Cueto, Mercedes CSIC ORCID ; Dorta, Enrique CSIC; Rovirosa, Juana; San Martín, Aurelio; Darias, José CSIC
Issue Date20-Jul-2002
PublisherAmerican Chemical Society
CitationOrganic Letters 4(17): 2949-2952 (2002)
AbstractEmpirical rules based on 13C and 1H NMR spectroscopy to determine the regiochemistry and geometry of the 1,2-bromochloro vinyl portion of naturally occurring or synthetic compounds containing this functionality are proposed. The key feature of the method comes from the comparison of the spectral data of the new monoterpene metabolite, prefuroplocamioid, isolated from Plocamium cartilagineum, with those of other marine monoterpenes, as well as with some model compounds found in the literature.
Description4 pages, 2 figures, 2 tables, 1 scheme.-- PMID: 12182596 [PubMed].-- Printed version published Aug 22, 2002.
Supporting information available: Spectral data for compound 1 and a detailed experimental procedure.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/ol026353f
Publisher version (URL)http://dx.doi.org/10.1021/ol026353f
URIhttp://hdl.handle.net/10261/13223
DOI10.1021/ol026353f
ISSN1523-7060
Appears in Collections:(IPNA) Artículos

Show full item record
Review this work

SCOPUSTM   
Citations

10
checked on May 18, 2022

WEB OF SCIENCETM
Citations

9
checked on May 19, 2022

Page view(s)

312
checked on May 25, 2022

Google ScholarTM

Check

Altmetric

Dimensions


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.