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Title

Alkynoates as a source of reactive alkylinides for aldehyde addition reactions

AuthorsArmas, Pedro de ; García-Tellado, Fernando ; Marrero-Tellado, José Juan ; Tejedor, David ; Maestro, Miguel A.; González-Platas, Javier
Issue Date15-May-2001
PublisherAmerican Chemical Society
CitationOrganic Letters 3(12): 1905-1908 (2001)
AbstractThe reaction (see figure) of activated alkynes with carbonyl compounds in the presence of a catalytic amount of a nucleophile leads to enol-protected functionalized propargyl alcohols and 1,3-dioxolane compounds by way of a mild carbon−carbon bond formation reaction.
Description4 pages, 1 table, 2 schemes.-- PMID: 11405741 [PubMed].-- Printed version published Jun 14, 2001.
Supporting information available: Experimental procedure and analytical and spectroscopic data for compounds 3 and 4. X-ray data for the acid derivative of 4 Z-syn Z = CO2Me, R1 = CH3(CH2)5, R2 = H.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/ol015951b
Publisher version (URL)http://dx.doi.org/10.1021/ol015951b
URIhttp://hdl.handle.net/10261/13222
DOI10.1021/ol015951b
ISSN1523-7060
Appears in Collections:(IPNA) Artículos
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