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Direct on-surface patterning of a crystalline laminar covalent organic framework synthesized at room temperature

AuthorsPeña Ruigómez, Alejandro de la; Stylianou, Kyriakos C. ; Carbonell, Carlos ; Maspoch, Daniel ; Zamora, Félix
Issue Date2015
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 21(30): 10666-10670 (2015)
AbstractWe report herein an efficient, fast, and simple synthesis of an imine-based covalent organic framework (COF) at room temperature (hereafter, RT-COF-1). RT-COF-1 shows a layered hexagonal structure exhibiting channels, is robust, and is porous to N2 and CO2. The roomtemperature synthesis has enabled us to fabricate and position low-cost micro- and submicropatterns of RT-COF-1 on several surfaces, including solid SiO2 substrates and flexible acetate paper, by using lithographically controlled wetting and conventional ink-jet printing.
Identifiersdoi: 10.1002/chem.201501692
e-issn: 1521-3765
issn: 0947-6539
Appears in Collections:(CIN2) Artículos
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