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Título: | Design and synthesis of a noninnocent multitopic catechol and pyridine mixed ligand: Nanoscale polymers and valence tautomerism |
Autor: | Guardingo, Mireia CSIC; Busqué, Félix; Novio, Fernando CSIC ORCID; Ruiz Molina, Daniel CSIC ORCID | Fecha de publicación: | 2015 | Editor: | American Chemical Society | Citación: | Inorganic Chemistry 54(14): 6776-6781 (2015) | Resumen: | The design and synthesis of a new redox-active ligand combining catechol and pyridine units have allowed the achievement of cobalt-based nanoscale coordination polymer particles in a single-step exhibiting a switchable valence tautomeric behavior and thermal hysteresis. The combination of polymerizing capabilities with redox-active responses in a unique ligand leads to the formation of nanoparticles exhibiting a gradual valence tautomeric interconversion in the 35-370 K temperature range. Using one single ligand to obtain these nanoparticles facilitates possible nanostructure formation methodologies. | Versión del editor: | http://dx.doi.org/10.1021/acs.inorgchem.5b00598 | URI: | http://hdl.handle.net/10261/131627 | DOI: | 10.1021/acs.inorgchem.5b00598 | Identificadores: | doi: 10.1021/acs.inorgchem.5b00598 issn: 0020-1669 e-issn: 1520-510X |
Aparece en las colecciones: | (CIN2) Artículos |
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Valence Tautomerism.pdf | 583,07 kB | Adobe PDF | Visualizar/Abrir |
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