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Title

Design and synthesis of a noninnocent multitopic catechol and pyridine mixed ligand: Nanoscale polymers and valence tautomerism

AuthorsGuardingo, Mireia ; Busqué, Félix; Novio, Fernando ; Ruiz Molina, Daniel
Issue Date2015
PublisherAmerican Chemical Society
CitationInorganic Chemistry 54(14): 6776-6781 (2015)
AbstractThe design and synthesis of a new redox-active ligand combining catechol and pyridine units have allowed the achievement of cobalt-based nanoscale coordination polymer particles in a single-step exhibiting a switchable valence tautomeric behavior and thermal hysteresis. The combination of polymerizing capabilities with redox-active responses in a unique ligand leads to the formation of nanoparticles exhibiting a gradual valence tautomeric interconversion in the 35-370 K temperature range. Using one single ligand to obtain these nanoparticles facilitates possible nanostructure formation methodologies.
Publisher version (URL)http://dx.doi.org/10.1021/acs.inorgchem.5b00598
URIhttp://hdl.handle.net/10261/131627
DOI10.1021/acs.inorgchem.5b00598
Identifiersdoi: 10.1021/acs.inorgchem.5b00598
issn: 0020-1669
e-issn: 1520-510X
Appears in Collections:(CIN2) Artículos
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