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http://hdl.handle.net/10261/12976
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dc.contributor.author | Tejedor, David | en_US |
dc.contributor.author | López-Tosco, Sara | en_US |
dc.contributor.author | González-Platas, Javier | en_US |
dc.contributor.author | García-Tellado, Fernando | - |
dc.date.accessioned | 2009-05-12T06:15:42Z | - |
dc.date.available | 2009-05-12T06:15:42Z | - |
dc.date.issued | 2007-06-09 | en_US |
dc.identifier.citation | Journal of Organic Chemistry 72(14): 5454-5456 (2007) | en_US |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10261/12976 | - |
dc.description | 3 pages, 1 figure, 1 table, 3 schemes.-- PMID: 17559282 [PubMed].-- Printed version published Jul 6, 2007. | - |
dc.description | Supporting information available at: http://pubs.acs.org/doi/suppl/10.1021/jo070764y | - |
dc.description | [General experimental and characterization data for compounds 4ab-ak, 4ba, 4bb, and 4bi and X-ray data for the derivative 4ak]. | - |
dc.description.abstract | A metal-free chemodifferentiating A2BB' 4CR manifold for the modular synthesis of tertiary skipped diynes is described. The manifold performs a triethylamine triggered reaction of alkyl propiolates and acid chlorides to assemble two units of each component in the form of two propargylic alkynoates, a tertiary alcohol, and an ester. A differentiated incorporation of the two acid chloride components ensures functional diversity in the final structure. In addition, the presence of two connected propargylic alkynoates provides a reactive platform for complexity generation. | - |
dc.description.sponsorship | This research was financially supported by the Spanish Ministerio de Educación y Ciencia and the European Regional Development Fund (CTQ2005-09074-C02-02). F.G.T. and D.T. are associate researchers at the Instituto Canario de Investigación del Cáncer (http://www.icic.es). D.T. is the recipient of a postdoctoral I3P fellowship from the Consejo Superior de Investigaciones Científicas. S.L.-T. thanks the Spanish MEC for a FPU grant. | - |
dc.format.extent | 2373 bytes | - |
dc.format.extent | 89606 bytes | - |
dc.format.mimetype | text/plain | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | - |
dc.rights | openAccess | en_US |
dc.title | Metal-free access to fully substituted skipped diynes. An efficient chemodifferentiating A2BB' 4CR manifold | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1021/jo070764y | - |
dc.relation.publisherversion | http://dx.doi.org/10.1021/jo070764y | - |
dc.contributor.funder | Ministerio de Educación y Ciencia (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Instituto Canario de Investigación del Cáncer | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
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Metal-Free_Access-Garcia_Tellado.pdf | 412,13 kB | Adobe PDF | Visualizar/Abrir |
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