Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/12976
COMPARTIR / EXPORTAR:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE

Invitar a revisión por pares abierta
Campo DC Valor Lengua/Idioma
dc.contributor.authorTejedor, Daviden_US
dc.contributor.authorLópez-Tosco, Saraen_US
dc.contributor.authorGonzález-Platas, Javieren_US
dc.contributor.authorGarcía-Tellado, Fernando-
dc.date.accessioned2009-05-12T06:15:42Z-
dc.date.available2009-05-12T06:15:42Z-
dc.date.issued2007-06-09en_US
dc.identifier.citationJournal of Organic Chemistry 72(14): 5454-5456 (2007)en_US
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/10261/12976-
dc.description3 pages, 1 figure, 1 table, 3 schemes.-- PMID: 17559282 [PubMed].-- Printed version published Jul 6, 2007.-
dc.descriptionSupporting information available at: http://pubs.acs.org/doi/suppl/10.1021/jo070764y-
dc.description[General experimental and characterization data for compounds 4ab-ak, 4ba, 4bb, and 4bi and X-ray data for the derivative 4ak].-
dc.description.abstractA metal-free chemodifferentiating A2BB' 4CR manifold for the modular synthesis of tertiary skipped diynes is described. The manifold performs a triethylamine triggered reaction of alkyl propiolates and acid chlorides to assemble two units of each component in the form of two propargylic alkynoates, a tertiary alcohol, and an ester. A differentiated incorporation of the two acid chloride components ensures functional diversity in the final structure. In addition, the presence of two connected propargylic alkynoates provides a reactive platform for complexity generation.-
dc.description.sponsorshipThis research was financially supported by the Spanish Ministerio de Educación y Ciencia and the European Regional Development Fund (CTQ2005-09074-C02-02). F.G.T. and D.T. are associate researchers at the Instituto Canario de Investigación del Cáncer (http://www.icic.es). D.T. is the recipient of a postdoctoral I3P fellowship from the Consejo Superior de Investigaciones Científicas. S.L.-T. thanks the Spanish MEC for a FPU grant.-
dc.format.extent2373 bytes-
dc.format.extent89606 bytes-
dc.format.mimetypetext/plain-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherAmerican Chemical Society-
dc.rightsopenAccessen_US
dc.titleMetal-free access to fully substituted skipped diynes. An efficient chemodifferentiating A2BB' 4CR manifolden_US
dc.typeartículoen_US
dc.identifier.doi10.1021/jo070764y-
dc.relation.publisherversionhttp://dx.doi.org/10.1021/jo070764y-
dc.contributor.funderMinisterio de Educación y Ciencia (España)-
dc.contributor.funderEuropean Commission-
dc.contributor.funderInstituto Canario de Investigación del Cáncer-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
Aparece en las colecciones: (IPNA) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato
Metal-Free_Access-Garcia_Tellado.pdf412,13 kBAdobe PDFVista previa
Visualizar/Abrir
Show simple item record

CORE Recommender

SCOPUSTM   
Citations

21
checked on 23-mar-2024

WEB OF SCIENCETM
Citations

21
checked on 26-feb-2024

Page view(s)

402
checked on 27-mar-2024

Download(s)

326
checked on 27-mar-2024

Google ScholarTM

Check

Altmetric

Altmetric


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.