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The biomimetic cyclization of melampomagnolide B

AuthorsGonzález, Antonio G.; Galindo, Antonio ; Afonso, M. Mar; Mansilla, Horacio ; López Rodríguez, Matías
Issue Date1988
CitationTetrahedron 44(14): 4585-4589 (1988)
AbstractMelampomagnolide B (9) was prepared and converted to the epimeric trans-(1αH,5βOH)-guaianolides (19) and 1,5-epoxygermacranolide (15).The 11,13-dihydroderivative (10) afforded (20) and (16). The biogenetic implications of this process are discussed.
Description5 pages, 2 figures, 2 schemes.
Supplementary material is obtainable on request from the Cambridge Crystallographic Data Centre (CCDC), University Chemical Laboratory, Lensfield Road, Cambridge.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4020(01)86161-5
Appears in Collections:(IPNA) Artículos
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