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Closed Access item Sequential Norrish type II photoelimination and intramolecular aldol cyclization of 1,2-diketones in carbohydrate systems: stereoselective synthesis of cyclopentitols

Authors:Álvarez-Dorta, Dimitri
León, Elisa I.
Kennedy, Alan R.
Riesco-Fagundo, Concepción
Suárez, Ernesto
Keywords:1,2-diketones, Aldol reaction, Carbohydrates, Photochemistry, Radicals
Issue Date:9-Oct-2008
Publisher:John Wiley & Sons
Citation:Angewandte Chemie - International Edition 47(46): 8917-8919 (2008)
Abstract:The photochemical behavior of 1,2-diketones differs considerably from that of monoketones and has received a great deal of attention from a theoretical viewpoint over the years.
Description:3 pages, 1 table, 3 schemes.-- PMID: 18846532 [PubMed].
Supporting information (33 pages) available at: http://www3.interscience.wiley.com/journal/121431876/suppinfo
Publisher version (URL):http://dx.doi.org/10.1002/anie.200803696
URI:http://hdl.handle.net/10261/12613
ISSN:1433-7851
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Appears in Collections:(IPNA) Artículos

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