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Title

Sequential Norrish type II photoelimination and intramolecular aldol cyclization of 1,2-diketones in carbohydrate systems: stereoselective synthesis of cyclopentitols

AuthorsÁlvarez-Dorta, Dimitri ; León, Elisa I. ; Kennedy, Alan R.; Riesco-Fagundo, Concepción ; Suárez, Ernesto
Keywords1,2-diketones
Aldol reaction
Carbohydrates
Photochemistry
Radicals
Issue Date9-Oct-2008
PublisherJohn Wiley & Sons
CitationAngewandte Chemie - International Edition 47(46): 8917-8919 (2008)
AbstractThe photochemical behavior of 1,2-diketones differs considerably from that of monoketones and has received a great deal of attention from a theoretical viewpoint over the years.
Description3 pages, 1 table, 3 schemes.-- PMID: 18846532 [PubMed].
Supporting information (33 pages) available at: http://www3.interscience.wiley.com/journal/121431876/suppinfo
Publisher version (URL)http://dx.doi.org/10.1002/anie.200803696
URIhttp://hdl.handle.net/10261/12613
DOI10.1002/anie.200803696
ISSN1433-7851
Appears in Collections:(IPNA) Artículos
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