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Título: | Synthesis, crystal structure and magnetic properties of a new cyanide-bridged mixed-valence copper(I)/copper(II) clathrate |
Autor: | Visinescu, Diana; Fabelo, Oscar CSIC ORCID; Ruiz-Pérez, Catalina; Lloret, Francesc; Julve, Miguel | Palabras clave: | Crystal structures Binuclear complex Cyanide bridge Magnetic properties Mixed-valence copper(I,II) complexes |
Fecha de publicación: | 2013 | Editor: | Elsevier | Citación: | Inorganic Chemistry Communication 35: 252-254 (2013) | Resumen: | A unique cyanide-bridge mixed-valence CuI/CuII clathrate of formula [CuI2(CN)3][{CuII(tren)}2(μ-CN)](CF3SO3)2 [tren = tris(2-aminoethyl)amine] containing cyanide-bridged [{CuII(tren)}2(μ-CN)]3 + binuclear cations stacked between anionic honeycomb layered copper(I) cyanide networks, was synthesized and structurally characterized by single crystal X-ray diffraction. Variable-temperature magnetic susceptibility studies showed that the cyanide bridge mediates a strong antiferromagnetic interaction between the copper(II) centers (J = − 160 cm− 1, the spin Hamiltonian being defined as H = − JSA⋅SB). | URI: | http://hdl.handle.net/10261/117885 | DOI: | 10.1016/j.inoche.2013.06.037 | Identificadores: | doi: 10.1016/j.inoche.2013.06.037 issn: 1387-7003 |
Aparece en las colecciones: | (ICMA) Artículos |
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