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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Yan Geng | - |
dc.contributor.author | Pfattner, Raphael | - |
dc.contributor.author | Campos García, Antonio | - |
dc.contributor.author | Hauser, Jürg | - |
dc.contributor.author | Laukhin, Vladimir | - |
dc.contributor.author | Puigdollers-González, Joaquim | - |
dc.contributor.author | Veciana, Jaume | - |
dc.contributor.author | Mas Torrent, Marta | - |
dc.contributor.author | Rovira, Concepció | - |
dc.contributor.author | Decurtins, Silvio | - |
dc.contributor.author | Liu, Shi-Xia | - |
dc.date.accessioned | 2015-07-01T13:47:25Z | - |
dc.date.available | 2015-07-01T13:47:25Z | - |
dc.date.issued | 2014-06-02 | - |
dc.identifier | doi: 10.1002/chem.201304688 | - |
dc.identifier | issn: 1521-3765 | - |
dc.identifier.citation | Chemistry - A European Journal 20(23): 7136- 7143 (2014) | - |
dc.identifier.uri | http://hdl.handle.net/10261/117448 | - |
dc.description.abstract | A compact and planar donor-acceptor molecule 1 comprising tetrathiafulvalene (TTF) and benzothiadiazole (BTD) units has been synthesised and experimentally characterised by structural, optical, and electrochemical methods. Solution-processed and thermally evaporated thin films of 1 have also been explored as active materials in organic field-effect transistors (OFETs). For these devices, hole field-effect mobilities of μFE=(1. 3±0.5)×10-3 and (2.7±0.4)×10-3 cm2 V s-1 were determined for the solution-processed and thermally evaporated thin films, respectively. An intense intramolecular charge-transfer (ICT) transition at around 495 nm dominates the optical absorption spectrum of the neutral dyad, which also shows a weak emission from its ICT state. The iodine-induced oxidation of 1 leads to a partially oxidised crystalline charge-transfer (CT) salt {(1)2I3}, and eventually also to a fully oxidised compound {1I3} 1/2I2. Single crystals of the former CT compound, exhibiting a highly symmetrical crystal structure, reveal a fairly good room temperature electrical conductivity of the order of 2 S cm-1. The one-dimensional spin system bears compactly bonded BTD acceptors (spatial localisation of the LUMO) along its ridge. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
dc.description.sponsorship | Financial support for this research by the Swiss National Science Foundation (Grant No. 200021–147143), the ERC StG 2012–306826 e-GAMES, the Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), and the DGI (Spain) through the project POMAS CTQ2010– 19501/BQU as well as TEC2011–27859-C02–01 is gratefully acknowledged. | - |
dc.publisher | John Wiley & Sons | - |
dc.rights | openAccess | - |
dc.subject | Electrical conductivity | - |
dc.subject | Tetrathiafulvalene–benzothiadiazole | - |
dc.subject | Donor–acceptor systems | - |
dc.subject | Organic field-effect transistor | - |
dc.subject | Charge transfer | - |
dc.title | A compact tetrathiafulvalene-benzothiadiazole dyad and its highly symmetrical charge-transfer salt: Ordered donor π-stacks closely bound to their acceptors | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/chem.201304688 | - |
dc.date.updated | 2015-07-01T13:47:25Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
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