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A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles

AuthorsMartínez-Prieto, Luis Miguel ; Urbaneja, C. ; Palma, Pilar ; Cámpora, Juan ; Philippot, Karine; Chaudret, Bruno
Issue Date2015
PublisherRoyal Society of Chemistry (Great Britain)
CitationChemical Communications, 51: 4647-4650 (2015)
AbstractThe betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the metal surface takes place through the carbodiimide moiety. The resulting RuNPs led to decarbonylation of THF and showed size selectivity for styrene hydrogenation.
Publisher version (URL)http://dx.doi.org/10.1039/C5CC00211G
Appears in Collections:(IIQ) Artículos
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