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Investigation of the chemical and morphological structure of thermally rearranged polymers

AuthorsSmith, Z. P.; Czenkusch, K.; Wi, S.; Gleason, K. L.; Hernández, G.; Doherty, C. M.; Konstas, K.; Bastow, T. J.; Alvarez, C.; Hill, A. J.; Lozano López, Ángel Emilio ; Paul, D. R.; Freeman, B. D.
Gas separation membranes
TR polymers
Issue Date2014
CitationPolymer 55: 6649-6657 (2014)
AbstractReacting ortho-functional poly(hydroxyimide)s via a high-temperature (i.e., 350 °C-450°C) solid-state reaction produces polymers with exceptional gas separation properties for separations such as CO2/CH4, CO2/N2, and H2/CH4. However, these reactions render these so-called thermally rearranged (TR) polymers insoluble in common solvents, which prevent the use of certain experimental characterization techniques such as solution-state nuclear magnetic resonance (NMR) from identifying their chemical structure. In this work, we seek to identify the chemical structure of TR polymers by synthesizing a partially soluble TR polymer from an ortho-functional poly(hydroxyamide). The chemical structure of this TR polymer was characterized using 1-D and 2-D NMR. By use of cross-polarization magic-angle spinning 13C NMR, the structure of the polyamide-based TR polymer was compared to that of a polyimide-based TR polymer with a nearly identical proposed structure. The NMR spectra suggest that oxazole functionality is formed for both of these TR polymers. Furthermore, gas permeation results are provided for the precursor polymers and their corresponding TR polymer. The differences in transport properties for these polymers result from differences in the isomeric nature of oxazole-aromatic linkages and morphological differences related to free volume and free volume distribution.
Identifiersdoi: 10.1016/j.polymer.2014.10.055
issn: 0032-3861
Appears in Collections:(ICTP) Artículos
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