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dc.contributor.authorCasal Banciella, María Dolores-
dc.contributor.authorDíez Díaz-Estébanez, María Antonia-
dc.contributor.authorÁlvarez García, Ramón-
dc.contributor.authorBarriocanal Rueda, Carmen-
dc.date.accessioned2009-03-12T12:31:26Z-
dc.date.available2009-03-12T12:31:26Z-
dc.date.issued2007-05-
dc.identifier.citationJournal of Analytical and Applied Pyrolysis 79(1/2): 161-168 (2007)en_US
dc.identifier.issn0165-2370-
dc.identifier.urihttp://hdl.handle.net/10261/11541-
dc.description8 pages, 8 figures, 7 tables. -- Available online 13 November 2006. -- Issue title: PYROLYSIS 2006: Papers presented at the 17th International Symposium on Analytical and Applied Pyrolysis (Budapest, Hungary, 22-26 May 2006)en_US
dc.description.abstractTwo coals of different rank and coking pressure characteristics together with a blend containing 50 wt% of each coal were employed for this study. High-temperature carbonizations in a movable wall oven of 250 kg capacity were carried out to assess the degree of dangerousness during coking. At the same time, the gas evolved during the process was condensed. In order to obtain the different layers that are formed during coking, partially coked charges were recovered from the oven. The central part of the charge was treated with organic solvents. Moreover, primary tar generated from the two coals and the blend was obtained by means of a Gray-King apparatus. The extract of the partially coked coal together with the high-temperature and the primary tars were studied by means of gas and liquid chromatography. It was found that the composition of the extract was similar to that of the primary tar, its composition depending on the coking pressure characteristics of the coals tested. By contrast, the high-temperature tar is similar for the coals and blend tested in the present work regardless of their rank or coking pressure characteristics.en_US
dc.description.sponsorshipThe authors thank the Ministerio de Ciencia y Tecnología – MCYT (project PPQ2001-1450) and the European Coal and Steel Community – ECSC (project 7220-PR/069) for financial support. MD Casal acknowledges Consejo Superior de Investigaciones Científicas – CSIC and Fondo Social Europeo for financial support (I3P Program).en_US
dc.format.extent22195 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.rightsclosedAccessen_US
dc.subjectCoalen_US
dc.subjectPyrolysisen_US
dc.subjectCoking pressureen_US
dc.subjectPrimary taren_US
dc.subjectHigh-temperature taren_US
dc.titleSuitability of Gray-King pyrolysis to evaluate coking pressureen_US
dc.typeartículoen_US
dc.identifier.doi10.1016/j.jaap.2006.10.001-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.jaap.2006.10.001en_US
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