English
español
Please use this identifier to cite or link to this item:
http://hdl.handle.net/10261/112887
Share/Impact:
Statistics |
![]() ![]() ![]() |
|
|
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |||
|
Title: | Ammonium-cobalt-nickel phosphates, NH4[Co1-xNixPO4]·H2O |
Authors: | Torre-Fernández, Laura; Trobajo, Camino ![]() ![]() ![]() |
Issue Date: | 2013 |
Publisher: | Elsevier |
Citation: | Journal of Solid State Chemistry 206: 75-84 (2013) |
Abstract: | The ammonium-cobalt-nickel phosphates, NH4[Co 1-xNixPO4]·H2O (x=0.00, 0.34, 0.59, 0.70, 1.00), and the deuterated forms, ND4[Co 1-xNixPO4]·D2O (x=0.00, 0.38, 0.48, 0.69, 0.85), have been synthesized under mild hydrothermal conditions and characterised using X-ray and neutron diffraction, chemical and thermal analysis, and magnetic measurements. Their crystal structures, including hydrogen positions, were determined by Rietveld refinement using single-crystal X-ray and neutron powder diffraction data. The space group of these orthorhombic crystals modifies as a function of their composition. The magnetic susceptibility and magnetization measurements of these ammonium-cobalt-nickel phosphates show antiferromagnetic behaviour, and the Neel temperature evolves from 5.5 K (x=0.00) up to 13.2 K (x=1.00). © 2013 Elsevier Inc. |
URI: | http://hdl.handle.net/10261/112887 |
DOI: | 10.1016/j.jssc.2013.07.039 |
Identifiers: | doi: 10.1016/j.jssc.2013.07.039 issn: 0022-4596 |
Appears in Collections: | (ICMA) Artículos (CINN) Artículos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | ![]() View/Open |
Show full item record
Review this work
Review this work
Related articles:
WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.