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Title

Fluorocarbons modulate the coordination sphere of f-element complexes

AuthorsÁlvarez, Santiago; Menjón, Babil
KeywordsFluorocarbons
Uranium
Secondary interactions
Stereochemistry
Lanthanides
Issue Date2014
PublisherWiley-VCH
CitationAngewandte Chemie - International Edition 53: 2810- 2811 (2014)
AbstractWeak yet influential: Fluorocarbons, the least coordinating of all halocarbons, establish secondary coordinative interactions with f elements. These interactions affect the stereochemistry of the complexes and provide examples of coordination polyhedra along distortion paths not seen before (see graphic). © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URIhttp://hdl.handle.net/10261/111778
DOI10.1002/anie.201310916
Identifiersdoi: 10.1002/anie.201310916
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ISQCH) Artículos
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