Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/110723
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | TLC-SERS of mauve, the first synthetic dye |
Autor: | Cañamares, María Vega ; Reagan, D.A.; Lombardi, John R.; Leona, M. | Palabras clave: | Synthetic dyes TLC SERS DFT Mauveine |
Fecha de publicación: | 2014 | Editor: | John Wiley & Sons | Citación: | Journal of Raman Spectroscopy 45: 1147- 1152 (2014) | Resumen: | Copyright © 2014 John Wiley & Sons, Ltd. Mauve was the first synthetic organic dyestuff to be manufactured industrially. It was synthesized in 1856 by William H. Perkin. It is composed by different molecules named mauveine A, B, B2 and C. In this study, the dye was synthesized, and its individual components were analyzed by ordinary Raman spectroscopy (both dispersive and Fourier-transform-), and surface-enhanced Raman spectroscopy, after separation by thin-layer chromatography. Only surface-enhanced Raman scattering (SERS) gave rise to satisfactory Raman spectra of the dye. Five different fractions were separated on the thin layer chromatography plate, and Raman and SERS measurements were carried out directly on each separated spot on the plate. As in the analysis of the raw product of the synthesis, only SERS gave high quality Raman spectra for the eluted spots. The assignment of the normal modes of mauveine was aided by performing density functional theory calculations. | URI: | http://hdl.handle.net/10261/110723 | DOI: | 10.1002/jrs.4508 | Identificadores: | doi: 10.1002/jrs.4508 issn: 1097-4555 |
Aparece en las colecciones: | (CFMAC-IEM) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
58
checked on 24-abr-2024
WEB OF SCIENCETM
Citations
49
checked on 29-feb-2024
Page view(s)
300
checked on 24-abr-2024
Download(s)
135
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.