Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/102522
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Díez, Blanca | - |
dc.contributor.author | Cuadrado, Purificación | - |
dc.contributor.author | Marcos-Fernández, Ángel | - |
dc.contributor.author | Prádanos, Pedro | - |
dc.contributor.author | Tena, Alberto | - |
dc.contributor.author | Palacio, Laura | - |
dc.contributor.author | Lozano López, Ángel Emilio | - |
dc.contributor.author | Hernández, Antonio | - |
dc.date.accessioned | 2014-09-26T08:47:43Z | - |
dc.date.available | 2014-09-26T08:47:43Z | - |
dc.date.issued | 2014 | - |
dc.identifier | doi: 10.1021/ie501649b | - |
dc.identifier | issn: 1520-5045 | - |
dc.identifier.citation | Industrial and Engineering Chemistry Research 53: 12809- 12818 (2014) | - |
dc.identifier.uri | http://hdl.handle.net/10261/102522 | - |
dc.description.abstract | Poly(o-acyloxyamide)s (PORAs) derived from a poly(o-hydroxyamide) from 2,2′-bis(3-amino-4-hydroxyphenyl)hexafluoropropane (APAF) diamine, APAF-POHA, have been synthesized and evaluated as gas separation materials. PORAs were synthesized from poly(o-hydroxyamide)s by derivatization of the free OH group with an aliphatic acid dichloride or dianhydride that allowed the introduction of acetyl or pivaloyl groups on their structure. All of them showed low-medium thermal stability due to a degradation of the amide moieties, and most of them (those synthesized from isophthaloyl dichloride (IPC), 2,2′-bis(4-carboxyphenyl) hexafluoropropane dichloride (6FC), and 4,4′-dicarboxydiphenylsulfone dichloride (DPSC)) showed good mechanical properties. The poly(o-acyloxyamide)s synthesized have shown good permselectivities for He/N2 and He/CH4 separations and very good permeability-selectivity balance for He/CO2 separation. The acetyl PORAs showed better permeability versus selectivity balances than the pivaloyl ones. Moreover, selectivity increased while permeability decreased in the sequence 6F-APAF > IP-APAF > DPS-APAF. Intersegmental distances, d-spacing, were shown to decrease along this sequence, obtaining a nice correlation between permeability and d-spacing. For the He/N2 and the He/CH4 pairs of gases, the best permeability-selectivity values are obtained for 6F-APAF-Ac with a He permeability of 33 barrer and selectivities of 84 and 106, respectively. DPS-APAF-Ac gives a He permeability of 13 barrer and a selectivity of 21 for the He/CO2 separation. | - |
dc.publisher | American Chemical Society | - |
dc.rights | closedAccess | - |
dc.title | Helium recovery by membrane gas separation using poly(o-acyloxyamide)s | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/ie501649b | - |
dc.date.updated | 2014-09-26T08:47:43Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
Aparece en las colecciones: | (ICTP) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
17
checked on 09-abr-2024
WEB OF SCIENCETM
Citations
18
checked on 29-feb-2024
Page view(s)
357
checked on 22-abr-2024
Download(s)
110
checked on 22-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.