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Direct evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexes

AuthorsCartes, M. Ángeles ; Rodríguez-Delgado, Antonio; Palma, Pilar ; Sánchez, Luis J. ; Cámpora, Juan ; CSIC - Unidad de Recursos de Información Científica para la Investigación (URICI)
Issue Date2014
CitationCatalysis Science and Technology 4: 2504-2507 (2014)
Abstract1H NMR studies on ethylene oligomerization catalysed by the neutral monoalkyl complex [Fe(Me)(iPrBIP)] allow direct observation of alkyl iron intermediates as well as reversible ethylene coordination to the metal center, providing for the first time experimental evidence for a coordination-insertion mechanism of iron-catalysed ethylene upgrade reactions. © 2014 the Partner Organisations.
Identifiersdoi: 10.1039/c4cy00612g
issn: 2044-4761
Appears in Collections:(IIQ) Artículos
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