2024-03-29T12:06:24Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1487602021-06-22T08:43:28Zcom_10261_46com_10261_3com_10261_115col_10261_299col_10261_368
A redox-active radical as an effective nanoelectronic component: stability and electrochemical tunnelling spectroscopy in ionic liquids
Rudnev, Alexander V.
Franco, Carlos
Crivillers, Núria
Seber, Gonca
Droghetti, Andrea
Rungger, Ivan
Pobelov, Ilya V.
Veciana, Jaume
Mas Torrent, Marta
Rovira, Concepció
European Commission
Swiss National Science Foundation
Centro de Investigación Biomédica en Red Bioingeniería, Biomateriales y Nanomedicina (España)
Ministerio de Economía y Competitividad (España)
Generalitat de Catalunya
European Cooperation in Science and Technology
CSIC - Unidad de Recursos de Información Científica para la Investigación (URICI)
Single-molecule electronics
Break junction
Transistor
Voltammetry
Conductance
Ferrocene
A redox-active persistent perchlorotriphenylmethyl (PTM) radical chemically linked to gold exhibits stable electrochemical activity in ionic liquids. Electrochemical tunnelling spectroscopy in this medium demonstrates that the PTM radical shows a highly effective redox-mediated current enhancement, demonstrating its applicability as an active nanometer-scale electronic component.
2017-04-24T12:01:36Z
2017-04-24T12:01:36Z
2016-10-28
artículo
Physical Chemistry Chemical Physics 18(40): 27733-27737 (2016)
1463-9076
http://hdl.handle.net/10261/148760
10.1039/C6CP05658J
http://dx.doi.org/10.13039/501100000780
http://dx.doi.org/10.13039/501100005053
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100002809
http://dx.doi.org/10.13039/501100000921
eng
Publisher's version
http://dx.doi.org/10.1039/C6CP05658J
Sí
info:eu-repo/grantAgreement/EC/FP7/618082
info:eu-repo/grantAgreement/EC/FP7/306826
info:eu-repo/grantAgreement/EC/H2020/642196
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013-40480-R
https://creativecommons.org/licenses/by/3.0/
openAccess
Royal Society of Chemistry (UK)