2024-03-29T12:40:11Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1996102020-05-26T04:30:54Zcom_10261_48com_10261_5col_10261_301
1,8-Hydrogen Atom Transfer Promoted by N-Radicals in (1-4)-O-Disaccharide Models
León, Elisa I.
Martín, Ángeles
Pérez-Martín, Inés
Suárez, Ernesto
Carbohydrates
Radical reactions
Hydrogen transfer
Radicals
The nitrogen-centered radical generated by reaction of an N-sulfonamidate, attached to C-6 of a hexopyranose in a disaccharide model, with (diacetoxyiodo)benzene (DIB) and iodine undergoes a novel regio- and stereoselective intramolecular 1,8-hydrogen atom transfer (HAT) reaction to promote the functionalization of remote positions.
This work was supported by the Gobierno de Canarias (Research Program SolSubC200801000192) and the Ministerio de Ciencia e Innovación (Research Program CTQ2010‐18244), co‐financed by the Fondo Europeo de Desarrollo Regional (FEDER). I. P.‐M. thanks the Ministerio de Ciencia e Innovación for support (Research Program PIE 200930I138).
2020-02-04T11:00:55Z
2020-02-04T11:00:55Z
2011-12
2020-02-04T11:00:56Z
artículo
http://purl.org/coar/resource_type/c_6501
European Journal of Organic Chemistry 36:7339-7345 (2011)
1434-193X
http://hdl.handle.net/10261/199610
10.1002/ejoc.201101146
1099-0690
Postprint
https://doi.org/10.1002/ejoc.201101146
Sí
open
Wiley-VCH