2024-03-28T11:16:11Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1574572017-12-18T13:57:28Zcom_10261_33com_10261_5col_10261_286
DIGITAL.CSIC
author
Frutos, Mercedes de
author
Avello, M. G.
author
Viso, Alma
author
Fernández de la Pradilla, Roberto
author
Torre, María C. de la
author
Sierra, Miguel A.
author
Gornitzka, H.
author
Hemmert, Catherine
funder
Ministerio de Economía, Industria y Competitividad (España)
2017-11-20T12:23:49Z
2017-11-20T12:23:49Z
2016
Organic Letters 18: 3570-3573 (2016)
http://hdl.handle.net/10261/157457
10.1021/acs.orglett.6b01555
http://dx.doi.org/10.13039/501100010198
Gold mesoionic carbenes having a chiral sulfoxide group attached to the C4 position of the five membered ring have been prepared and tested as catalysts in the cycloisomerization of enynes. These new catalysts are very efficient, with the sulfoxide moiety playing a key role in their activity and the N1-substituent in control of the regioselectivity of these processes.
eng
closedAccess
Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity
artículo
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URL
https://digital.csic.es/bitstream/10261/157457/1/accesoRestringido.pdf
File
MD5
42637ae8545636bc41605c1740a9a84e
15753
application/pdf
accesoRestringido.pdf