2024-03-29T12:01:39Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/943802021-09-22T12:28:09Zcom_10261_89com_10261_3col_10261_342
00925njm 22002777a 4500
dc
Aguirre-Díaz, Lina María
author
Iglesias, Marta
author
Snejko, Natalia
author
Gutiérrez-Puebla, Enrique
author
Monge, M. Ángeles
author
2013
Two new Indium MOFs with the bending multicarboxylate ligand H 2dpmda as a linker and different N-donor ancillary ligands were obtained; the two compounds are isoreticular with 2D-hcb uninodal 3-connected nets. Comparison of their activity in cyanosilylation reactions with another eight In-MOFs is also reported. Eight out of the ten resulted in being good catalysts under mild and environmentally friendly conditions. Correlations between indium coordination number (CN), framework topology and catalytic activity are made and discussed, demonstrating that among the studied MOFs, the indium material named InPF-6 with the formula [In2(dpa) 3(1,10-phen)2]·H2O is the most effective catalyst. A possible catalytic mechanism is discussed. © 2013 The Royal Society of Chemistry.
CrystEngComm 15(45): 9562-9571 (2013)
http://hdl.handle.net/10261/94380
10.1039/C3CE41123K
Indium metal-organic frameworks as catalysts in solvent-free cyanosilylation reaction