2024-03-28T18:28:15Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/807772021-10-27T11:57:24Zcom_10261_46com_10261_3com_10261_81com_10261_5col_10261_299col_10261_334
00925njm 22002777a 4500
dc
Mata, Ignasi
author
Alkorta, Ibon
author
Molins, Elies
author
Espinosa, Enrique
author
2012
Stronger than you'd think: Ab initio calculations reveal that hydrogen bonds can lock phosphates into stable gas-phase complexes, showing that hydrogen bonding can overcome anion-anion repulsion. These complexes present a large energetic barrier of dissociation (see picture). The stability of the complexes can be explained in terms of the electrostatic interaction in the hydrogen-bond region. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Chemphyschem : a European journal of chemical physics and physical chemistry 13: 1421- 1424 (2012)
http://hdl.handle.net/10261/80777
10.1002/cphc.201200068
Electrostatics at the origin of the stability of phosphate-phosphate complexes locked by hydrogen bonds