2024-03-29T10:38:26Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/2057822020-04-30T07:58:10Zcom_10261_35com_10261_5col_10261_288
2020-03-30T10:38:57Z
urn:hdl:10261/205782
In-situ synthesis of hydrogen peroxide in tandem with selective oxidation reactions: A mini-review
Puértolas Lacambra, Begoña
Hill, Alfred K.
García Martínez, Tomás
Solsona, Benjamín
Torrente-Murciano, Laura
Ministerio de Economía y Competitividad (España)
European Commission
Engineering and Physical Sciences Research Council (UK)
Ministerio de Educación (España)
Puértolas Lacambra, Begoña [0000-0002-9468-3142]
Hill, Alfred K. [0000-0003-4324-3822]
García Martínez, Tomás [0000-0003-4255-5998]
Solsona, Benjamín [0000-0001-7235-2038]
Torrente-Murciano, Laura [0000-0002-7938-2587]
Green chemistry
Hydrogen peroxide
In-situ synthesis
Selective oxidation
Tandem systems
7 Figuras, 6 Tablas
One-pot combination of the in-situ generation of hydrogen peroxide (H2O2) with selective oxidation reactions enhances the environmental and economic attractiveness of the use of H2O2 as green oxidant at industrial scale. This tandem reaction improves not only the safety aspects associated to H2O2 storage and transportation but also reduces the capital and operation costs. This review covers the progress in the field focussing on the areas of catalysis development, mechanistic understanding and engineering approaches (such as membrane reactors) for specific systems involving epoxidation of propylene oxide, hydroxylation of benzene, oxygenate synthesis from methane and Fenton processes, highlighting the main challenges to overcome in the near future.
2020-03-30T10:38:57Z
2020-03-30T10:38:57Z
2014-04-29
artículo de revisión
Catalysis Today 248: 115-127 (2014)
0920-5861
http://hdl.handle.net/10261/205782
10.1016/j.cattod.2014.03.054
http://dx.doi.org/10.13039/501100000266
http://dx.doi.org/10.13039/501100000780
http://dx.doi.org/10.13039/501100003329
eng
Publisher's version
http://dx.doi.org/10.1016/j.cattod.2014.03.054
Sí
https://creativecommons.org/licenses/by/3.0/
openAccess
Elsevier BV