2024-03-28T21:52:25Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1863512021-11-22T13:07:14Zcom_10261_89com_10261_3col_10261_342
2019-07-18T10:29:36Z
urn:hdl:10261/186351
Densely packed ZnTPPs monolayer on the rutile TiO2(110)-(1 × 1) surface: adsorption behavior and energy level alignment
Rangan, Sylvie
Ruggieri, Charles
Bartynski, Robert
Martínez, José I.
Flores, Fernando
Ortega, José
European Research Council
Ministerio de Economía y Competitividad (España)
National Science Foundation (US)
The adsorption of a densely packed zinc(II) tetraphenylporphyrin monolayer on a rutile TiO(110)-(1 × 1) surface has been studied using a combination of experimental and theoretical methods, aimed at analyzing the relation between adsorption behavior and barrier height formation. The adsorption configuration of ZnTPP was determined from scanning tunnel microscopy (STM) imaging, density functional theory (DFT) calculations, and STM image simulation. The corresponding energy alignment was experimentally determined from X-ray and UV-photoemission spectroscopies and inverse photoemission spectroscopy. These results were found in good agreement with an appropriately corrected DFT model, pointing to the importance of local bonding and intermolecular interactions in the establishment of barrier heights.
2019-07-18T10:29:36Z
2019-07-18T10:29:36Z
2016-03-03
2019-07-18T10:29:36Z
artículo
Journal of Physical Chemistry C 120(8): 4430-4437 (2016)
http://hdl.handle.net/10261/186351
10.1021/acs.jpcc.5b12736
http://dx.doi.org/10.13039/100000001
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100000781
26998188
eng
https://doi.org/10.1021/acs.jpcc.5b12736
Sí
info:eu-repo/grantAgreement/EC/FP7/610256
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-59966-R
closedAccess
American Chemical Society