2024-03-28T13:06:17Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1732932022-01-31T11:06:36Zcom_10261_28457com_10261_3com_10261_84com_10261_5col_10261_28462col_10261_337
2018-12-17T10:06:49Z
urn:hdl:10261/173293
The ability of a fibrous titanium oxophosphate for nitrogen-adsorption above room temperature
García-Glez, Jorge
Amghouz, Zakariae
Silva, Iván da
Ania, Conchi O.
Parra, José B.
Trobajo, Camino
García-Granda, Santiago
Ministerio de Economía y Competitividad (España)
European Commission
Principado de Asturias
TiO(PO)·2HO (1), a three-dimensional titanium oxophosphate, thermally transforms to TiO(PO) (2), a fibrous novel compound. The crystal structure of 2 was solved ab initio using powder X-ray diffraction data (triclinic, P1, a = 5.0843(1) Å, b = 8.6121(2) Å, c = 9.6766(2) Å, α = 74.501(2)°, β = 76.146(2)°, γ = 74.488(3)°, Z = 2). Compound 2, containing both 4- and 6-fold coordinated titanium atoms, shows measurable thermally activated nitrogen-adsorption. To our knowledge, the process described here constitutes the first example of nitrogen-fixation by an inorganic material at above-ambient temperature.
2018-12-17T10:06:49Z
2018-12-17T10:06:49Z
2017
2018-12-17T10:06:50Z
artículo
Chemical Communications 53(14): 2249-2251 (2017)
http://hdl.handle.net/10261/173293
10.1039/C6CC07518E
http://dx.doi.org/10.13039/501100000780
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/100011941
eng
Sí
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-40950-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-78155-C2-1-R
closedAccess
Royal Society of Chemistry (UK)